Hazardous Materials
The PV cell manufacturing process includes a number of hazardous materials, most of which are used to clean and purify the semiconductor surface. These chemicals, similar to those used in the general semiconductor industry, include hydrochloric acid, sulfuric acid, nitric acid, hydrogen fluoride, 1,1,1-trichloroethane, and acetone. The amount and type of chemicals used depends on the type of cell, the amount of cleaning that is needed, and the size of silicon wafer [4]. Workers also face risks associated with inhaling silicon dust. Thus, PV manufactures must follow U.S. laws to ensure that workers are not harmed by exposure to these chemicals and that manufacturing waste products are disposed of properly.
Thin-film PV cells contain a number of more toxic materials than those used in traditional silicon photovoltaic cells, including gallium arsenide, copper-indium-gallium-diselenide, and cadmium-telluride[5]. If not handled and disposed of properly, these materials could pose serious environmental or public health threats. However, manufacturers have a strong financial incentive to ensure that these highly valuable and often rare materials are recycled rather than thrown away.
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